Boiler Water Treatment; Industrial & Process Applications
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Boiler Water Treatment - Industrial & Process Applications

Boiler Water Treatment - In this short paper we take a brief look at industrial boiler water treatment and the management of steam boilers from an industrial perspective. We examine some of the problems that can occur when steam boilers are used in industrial and process situations. We also look at solutions to the problems that arise with steam boiler systems, specific products and where they are used, how these solutions are applied, and more.

What is steam?

Steam is vaporised water, being part gas, part liquid. Steam itself is usually interspersed with minute droplets of water in its liquid state, which gives it a white, cloudy appearance. In industrial and process situations, steam is often generated using water boilers that are heated to create steam under controlled conditions. The energy generated is then transferred and used in many different ways.

In nature, steam is produced by the heating of underground water by volcanic processes and is emitted from hot springs, geysers, fumaroles, and certain types of volcanoes.


Advanced Chemical Technologies

Steam is used as a heat transfer medium in several industries including food, paper, process, chemical manufacture ...etc. In industry steam is produced by water boilers, which come in all shapes, sizes, types and pressures and the water within them likewise. This is what makes the life of a water treatment specialist interesting....having to deal with all the alternatives and know all the ways of treating those alternatives.

Why is boiler water used?

Steam under pressure is at elevated temperatures, greater than 100C and therefore can be used to transfer energy to different parts of a system. This energy can then be used to cook, create energy for chemical reactions, heat water and a myriad of other uses. Steam being "pure" water dissolves other materials into it very easily and it is these other materials that cause problems requiring treatments. Materials such as metals from the system, Oxygen and Carbon Dioxide to name but a few.

What problems arise and how do they occur?

There are several problems within a boiler system some of which require chemical treatment or other mechanical means to overcome them. The major problems are:

    • Scale
    • Corrosion
    • Boiler Water Carryover
    • Sludge Deposition

These can cause problems in all parts of the system starting with the feed tank leading through the boiler and into the condensate system. The problems arise from the quality of the water used within the steam raising system and the manner in which the system is operated and hence it is not only chemical issues that need to be addressed.

What happens if problems are not treated?

In extreme cases is has been known for steam boilers to explode causing much damage and even death. So it is for this reason that strict standards have arisen on how to treat and maintain boilers and associated systems. Then there are efficiency problem with excess fuel being used to raise the steam or leaks causing loss of water, chemicals and energy from the system. All of these issues are avoidable with simple chemicals and good maintenance regimes.

What Accepta products are available to resolve these problems and how do they work?

Accepta has an extensive range of high performance, technically advanced bolier products developed to help overcome the problems outlined above, including:

Oxygen scavengers to absorb oxygen thus preventing oxygen corrosion

  • Tannin Scavenger - Accepta 2212 is not dependant on the feed-water temperature and being organic it does not add to the boiler water conductivity so reducing the need for blowdown (compared with sulphite) ... tannin oxygen scavenger >>
  • Tannin Scavenger - Accepta 2812 is an excellent tannin based oxygen scavenger developed specifically for steam boilers and feed-water systems. Accepta 2812 does not add to the boiler water conductivity so reducing the need for blowdown (compared with sulphite) ... tannin oxygen scavenger >>
  • DEHA - Accepta 2061 provides outstanding protection from oxygen corrosion along with excellent feed-water and boiler system passivation. It can be used as a replacement for hydrazine in any boiler up to 125 bar without the associated safety hazards and handling precautions. Accepta 2061 is volatile and alkaline, contributing no dissolved solids or ammonia to the boiler system ... DEHA >>
  • DEHA - Accepta 2323 is a superior quality DEHA and hydroquinone based oxygen scavenger and condensate line protection product ... DEHA >>
  • Carbohydrazide - Accepta 2565 is an organic corrosion inhibitor used for scavenging oxygen and passivating metal surfaces. It can be used as a direct replacement for hydrazine in any boiler without the associated safety hazards and handling precautions. It can be used in boilers of any pressure, up to and including supercritical (220 bar g), and can be fed into feed-waters used for spray attemperation ... carbohydrazide >>
  • Catalysed Sodium Sulphite - Accepta 2972 is an efficient catalysed sodium sulphite product used to absorb oxygen in steam boiler systems. Dose ideally to feed tank to allow time for the oxygen to be absorbed before entering the steam boiler ... catalysed sodium sulphite >>
  • Multifunctional Sulphite - Accepta 2879 is an excellent multifunctional product developed for boilers and boiler water systems. Accepta 2879 contains catalysed bisulphite, for rapid and complete oxygen scavenging, phosphates for the control of precipitation, and powerful antiscalants and dispersants to mobilise hardness or iron oxide sludges and prevent thereby prevent scale ... multifunctional >>
  • Multifunctional Treatment - Accepta 2889 is a very versatile, combined tannin and carbonate based multi-functional water treatment product developed for use in boilers and closed circuit heating systems ... multifunctional >>
  • Sulphite with Alkalinity Builder - Accepta 2897 is a superior quality sulphite based water treatment product with added caustic, developed for use in steam boiler applications ... sulphite plus alkalinity builder >>
  • Steam Boiler Tannin - Accepta 2319 is a superior, blended liquid water treatment product based on organic tannins, polymer sludge, conditioners and alkali. Developed for steam boilers and LPHW systems, Accepta 2319 can be used with softened or moderately hard make-up, and in many instances provides a complete balanced treatment by itself ... steam tannin >>
  • Tannin - Accepta 2320 is an excellent, blended liquid treatment for the control of scale and corrosion in steam boiler systems. Accepta 2320 is based on organic tannin, polymer sludge conditioners and alkali ... multifunctional tannin >>
  • Tannin Based Oxygen Scavenger - Accepta 2812 is a tannin based oxygen scavenger. It is not dependant on the feed-water temperature and does not add to boiler water conductivity so reducing the need for blowdown ... tannin oxygen scavenger >>

Sludge conditioners to help prevent suspended solids baking onto heat transfer surfaces causing loss of efficiency

  • Polymer Sludge Control - Accepta 2814 is a versatile polymer based product developed as a steam boiler scale inhibitor and internal metal passivator. Accepta 2814 can also be used in systems up to 70 bar g.(1000psi) and complies with FDA regulations. It is best to use this product on clean boilers as it may remove existing scale deposits ... polymer sludge control >>
  • Combined Phosphate and Polymer Treatment for Steam Boilers - Accepta 2112 has been developed to be used as a scale inhibitor and suspended solids control agent. This product is best for softened and low hardness water. The phosphate reacts with the hardness whilst the polymer provides transport of the calcium, magnesium, iron, phosphate and silica, preventing scales adhering to the metal surfaces ... phosphate polymer >>
  • Multifunctional Sulphite for Boilers - Accepta 2879 is an excellent multifunctional product developed for boilers and boiler water systems. Accepta 2879 contains catalysed bisulphite, for rapid and complete oxygen scavenging, phosphates for the control of precipitation, and powerful antiscalants and dispersants to mobilise hardness or iron oxide sludges and prevent thereby prevent scale ... multifunctional sulphite >>
  • Polymer/Caustic Boiler Treatment - Accepta 2815 is a superior treatment product for boilers and boiler systems. Accepta 2815 comprises a liquid formulation containing an alkali and effective sludge conditioner ... polymer caustic >>
  • Polymer/Caustic - Accepta 2338 is a superior treatment product for boilers and boiler systems. Accepta 2338 comprises a liquid formulation containing an alkali and effective sludge conditioner ... polymer caustic >>
  • Sludge Conditioner - Accepta 2311 is a superior, blended liquid treatment developed as a sludge conditioner for the treatment of boiler waters. Accepta 2311 is based on sodium hexa-metaphosphate and polymeric sludge conditioners ... boiler sludge conditioner >>
  • Scale Dispersant/Sludge Conditioner for Steam Boilers and Cooling Systems - Accepta 2318 is a superior water treatment product comprising a specially blended mixture of polymeric sludge conditioners developed for use in steam boilers and cooling water systems ... scale dispersant and sludge conditioner >

pH control products to help prevent corrosion

  • Caustic Based pH Adjuster - Accepta 2013 is an excellent, concentrated sodium hydroxide (40%) based product for use as pH adjuster in boiler water treatment ... caustic pH adjuster >>
  • Sulphite with Alkalinity Builder - Accepta 2897 is a superior quality sulphite based water treatment product with added caustic, developed for use in steam boiler applications ... sulphite with alkalinity builder >>
  • 25% Caustic pH Adjuster - Accepta 2335 is a superior quality, caustic based product that can be used as a pH adjuster for steam boilers, effluent systems or any other process requiring pH adjustment ... pH adjuster >>
  • Caustic pH Adjuster - Accepta 2339 is a superior quality, caustic based product that can be used as a pH adjuster for steam boilers, effluent systems or any other process requiring pH adjustment ... pH adjuster >>
  • Caustic pH Adjuster - Accepta 2599 is a superior quality, caustic based product that can be used as a pH adjuster for steam boilers, effluent systems or any other process requiring pH adjustment ... pH adjuster >>
  • Polymer/Caustic Boiler Treatment - Accepta 2815 is a superior treatment product for boilers and boiler systems. Accepta 2815 comprises a liquid formulation containing an alkali and effective sludge conditioner ... polymer caustic >>
  • Polymer/Caustic - Accepta 2338 is a superior treatment product for boilers and boiler systems. Accepta 2338 comprises a liquid formulation containing an alkali and effective sludge conditioner ... polymer caustic >>
  • Alkalinity Builder - Accepta 2307 is an excellent, strong alkaline boiler water treatment developed for use in the control of feedwater pH, neutralising any acid present and contributing to alkalinity levels ... alkalinity builder >>

Antifoams to minimise boilerwater carryover

  • Anti-foam for Steam Boilers - Accepta 2586 has been developed for steam boiler applications and prevents boiler water carryover due to foaming ... steam anti-foam >>

Amines to protect the condensate system from oxygen and carbon dioxide corrosion

  • Neutralising Amine - Accepta 2328 is a cyclohexylamine based neutralising amine condensate line treatment for boilers. Accepta 2328 is suitable for use up to 2400psig. Accepta 2328 is FDA Regulation 21 CFR 173.310 compliant ... neutralising amine >>
  • Neutralising Amine Condensate Line Treatment - Accepta 2587 is a cyclohexylamine based neutralising amine condensate line treatment for boilers ... neutralising amine >>
  • Mixed Neutralising Amine Boiler Water Treatment - Accepta 2589 is a superior quality boiler water treatment product. Accepta 2589 comprises a mixture of cyclohexylamine and morpholine neutralising amine condensate line treatment for boiler systems up to 170 barg ... neutralising amine >>
  • Cyclohexylamine and Morpholine Neutralising Amine Condensate Line Protection - Accepta 2329 is an excellent, mixed filming and neutralising amine product developed for optimal condensate line protection in boiler systems up to 400 barg. Accepta 2329 forms a water repellent protective film on metal surfaces whilst also neutralising the condensate. It also acts to neutralise the carbon dioxide and films to prevent oxygen corrosion within the condensate, reducing both maintenance costs and the chances of boiler failure caused by metallic corrosion ... cyclohexylamine - morpholine neutralising amine >>
  • Cyclohexylamine and Morpholine Neutralising Amine Condensate Line Protection - Accepta 2820 is a superior quality boiler water treatment product. Accepta 2820 comprises a mixture of cyclohexylamine and morpholine neutralising amine condensate line treatment for boiler systems up to 170 barg. Accepta 2820 neutralises carbon dioxide within the condensate system. Accepta 2820 returns to boiler feed tank with condensate so will raise the feed pH slightly ... cyclohexylamine and morpholine neutralising amine >>
  • Mixed Neutralising Amine Boiler Water Treatment - Accepta 2589 is a superior quality boiler water treatment product. Accepta 2589 comprises a mixture of cyclohexylamine and morpholine neutralising amine condensate line treatment for boiler systems up to 170 barg ... neutralising amine >>

Resin cleaners for treating base exchange softeners

  • Base Exchange Resin Cleaner for Water Softeners - Accepta 2590 is a highly effective water softener resin cleaner specifically designed to remove iron fouling from base exchange softener resins ... base exchange cleaner >>
  • Resin Cleaner for Water Softeners - Accepta 2325 is a highly efficient water softener resin cleaner specifically designed to remove iron fouling from base exchange softener resins ... water softener resin cleaner >

How are Accepta's products applied?

All products are ideally dosed continuously using a dosing pump and tank. For optimum consumption they should be linked to a water meter on the feedwater to ensure they are only dosed when needed, and not under or over dosed. Some products should be dosed to the feed water, whilst others to the steam header depending on product system and the site specific problems faced, please consult Accepta for more details.

What are the benefits of using Accepta products?

Accepta's products should be used as part of a planned maintenance regime and help to optimise and extend the life of plant and equipment, hence reducing operating costs to a minimum.

Own label services

Accepta’s own/white label services offer you the opportunity of having our high quality, manufactured products branded as your own. All Accepta products can be re-branded with your company name, logo, contact details, and more included on each consignment and, if required delivered direct to a site of your choice with your own delivery paperwork. If you would like to learn more about our specialist own/white label services please call us on +44 (0) 161 877 23340 or e-mail info@accepta.com.

Additional information & technical support

For further information, technical support and advice please call Accepta on +44 (0) 161 877 2334 or e-mail info@accepta.com. For additional products, specifications, product data and MSDS's please review our products pages.

 

 

 

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